Selektivnost' Reaktsii Nitrovaniya Alkilbenzolov: Eksperimental'nyy I Kvantovokhimicheskiy Analiz Vliyaniya Organicheskikh Rastvoriteley - Evgeniy Krylov - Books - LAP LAMBERT Academic Publishing - 9783848441594 - April 6, 2012
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Evgeniy Krylov
Selektivnost' Reaktsii Nitrovaniya Alkilbenzolov: Eksperimental'nyy I Kvantovokhimicheskiy Analiz Vliyaniya Organicheskikh Rastvoriteley Russian edition

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Odnim iz effektivnykh metodov vozdeystviya na selektivnost' khimicheskikh reaktsiy yavlyaetsya upravlenie sostavom i svoystvami reaktsionnoy sredy. Monografiya posvyashchena issledovaniyu zakonomernostey reaktsii nitrovaniya alkilbenzolov v binarnykh sredakh na osnove organicheskikh rastvoriteley. Nitroalkilbenzoly predstavlyayut soboy predshestvenniki v sinteticheskikh protsessakh pri poluchenii krasiteley, lekarstvennykh preparatov, vysokoenergeticheskikh veshchestv, vysokomolekulyarnykh termostoykikh soedineniy. Diagnostika veroyatnykh mekhanizmov, ustanovlenie usloviy tselenapravlennogo sinteza nitroalkilbenzolov sochetayutsya s issledovaniem selektivnosti i kvantovokhimicheskim raschetom. Proveden analiz zakonomernostey aromaticheskogo nitrovaniya, rassmotreny reagenty, sredy i mekhanizmy. Sistematicheski issledovana reaktsiya nitrovaniya alkilbenzolov v politermicheskikh usloviyakh, opredeleny selektivnosti i vykhody tselevykh produktov. Diagnostika mekhanizmov osnovana na sootnoshenii selektivnostey, dannykh po konkurentnomu nitrovaniyu pary mezitilen/durol i kvantovokhimicheskom analize reaktsii. Ustanovleno, chto vozmozhna realizatsiya kak klassicheskogo mekhanizma Ar-SE2, tak i mekhanizma odnoelektronnogo perenosa (SET).

Media Books     Paperback Book   (Book with soft cover and glued back)
Released April 6, 2012
ISBN13 9783848441594
Publishers LAP LAMBERT Academic Publishing
Pages 148
Dimensions 150 × 9 × 225 mm   ·   238 g
Language German  

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