Oxidative Palladium (Ii)-catalyzed Carbocyclization: Control of Alkene Geometry or Relative Configuration - Sandeep Reddy Kandukuri - Books - LAP LAMBERT Academic Publishing - 9783848498802 - August 14, 2013
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Oxidative Palladium (Ii)-catalyzed Carbocyclization: Control of Alkene Geometry or Relative Configuration


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The present work is dedicated to the development and application of oxidative palladium(II)-catalyzed carbocyclizations. A general procedure for an aerobic palladium(II)-catalyzed endo cyclization of indole derivatives is presented. Further application of this new methodology in the synthesis of C-2 alkenylated indoles in diastereomerically pure form is also reported. The other methodologies involves hydroxy-directed diastereotopic group selection of prochiral bis(homoallylic) alcohols and enantioselective Fujiwara?Moritani cyclizations. In addition to this, the book also details on the indole directed aerobic dehydrogenation of cyclohexenes.

Media Books     Paperback Book   (Book with soft cover and glued back)
Released August 14, 2013
ISBN13 9783848498802
Publishers LAP LAMBERT Academic Publishing
Pages 280
Dimensions 150 × 16 × 226 mm   ·   435 g
Language German